Instead of a small-scale field test, Cao and Caldeira decided to model iron fertilization using the ocean GCM from Lawrence Livermore National Laboratory. To account for uncertainties, they chose to calculate an upper bound on iron fertilization rather than a most likely scenario. That is, they maxed out phytoplankton growth until something else became the limiting factor – in this case, phosphates. On every single cell of the sea surface, the model phytoplankton were programmed to grow until phosphate concentrations were zero.
A 2008-2100 simulation implementing this method was forced with CO2 emissions data from the A2 scenario. An otherwise identical A2 simulation did not include the ocean fertilization, to act as a control. Geoengineering modelling is strange that way, because there are multiple definitions of “control run”: a non-geoengineered climate that is allowed to warm unabated, as well as preindustrial conditions (the usual definition in climate modelling).
Without any geoengineering, atmospheric CO2 reached 965 ppm by 2100. With the maximum amount of iron fertilization possible, these levels only fell to 833 ppm. The mitigation of ocean acidification was also quite modest: the sea surface pH in 2100 was 7.74 without geoengineering, and 7.80 with. Given the potential side effects of iron fertilization, is such a small improvement worth the trouble?
Unfortunately, the ocean acidification doesn’t end there. Although the problem was lessened somewhat at the surface, deeper layers in the ocean actually became more acidic. There was less CO2 being gradually mixed in from the atmosphere, but another source of dissolved carbon appeared: as the phytoplankton died and sank, they decomposed a little bit and released enough CO2 to cause a net decrease in pH compared to the control run.
In the diagram below, compare the first row (A2 control run) to the second (A2 with iron fertilization). The more red the contours are, the more acidic that layer of the ocean is with respect to preindustrial conditions. The third row contains data from another simulation in which emissions were allowed to increase just enough to offest sequestration by phytoplankton, leading to the same CO2 concentrations as the control run. The general pattern – iron fertilization reduces some acidity at the surface, but increases it at depth – is clear.
The more I read about geoengineering, the more I realize how poor the associated cost-benefit ratios might be. The oft-repeated assertion is true: the easiest way to prevent further climate change is, by a long shot, to simply reduce our emissions.